A bifunctional chiral [2]catenane based on 1,1-binaphthyl-phosphates

A novel [2]catenane was synthesised by ring-closing metathesis from a Ca-bisphosphate template. The resulting interlocked structure features two chiral 1,1-binaphthyl-phosphates, leading to a bifunctional catenane structure. Initial binding studies point at the applicability of such mechanically interlocked bisphosphates as artificial receptors for dicationic guest molecules. A novel [2]catenane, featuring two chiral 1,1-binaphthyl-phosphates, was synthesised by ring-closing metathesis. The resulting bifunctional catenane was used as a chiral interlocked host for the binding of dicationic guest molecules.