Aging of glass powder surface

Glass powder (GP) obtained by grinding waste bottle glass has been recently introduced in construction materials as a supplementary cementing material (SCM). The behavior of SCMs strongly depends on surface chemistry, which governs their reactivity. The freshly ground glass (FGP) was analyzed by X-ray photoelectron spectroscopy (XPS) and changes in the chemical composition of its surface were monitored over time up to one year. The carbonation level that could affect the long-term reactivity of GP was also assessed. The results indicate a higher sodium content of the surface of the early milled glass. Surficial sodium and calcium contents tend to decrease over time with a negligible level of carbonation after one year. Furthermore, in order to assess the reactivity of GP in cementitious media over time, the fresh and hardened properties of mortars made with 20% FGP and two-year-old GP (OGP) as partial replacement of cement were characterized. The FGP mortar had reactivity slightly higher than that of the OGP with early setting due to surficial alkalis. Both GPs, however, had similar pozzolanic properties, particularly with a high water-to-binder (w/b), suggesting that age does not affect GP reactivity, at least in a cementitious medium. •The grinding of glass induces the migration of alkali ions on the surface of the glass powder (GP)•Aging causes Na- and Ca-depletion on the surface with low carbonation level•No difference in the chemical composition of the bulk GP is observed over time•Replacing 20 % of OPC by the freshly ground glass results in an acceleration of the early hydration•Aging seems to improve the long term reactivity of GP