Thermal Cyclization of Phenylallenes That Contain ortho-1,3-Dioxolan-2-yl Groups: New Cascade Reactions Initiated by 1,5-Hydride Shifts of Acetalic HAtoms

A series of 2-(1,3-dioxolan-2-yl)phenylallenes that contained a range of substituents (alkyl, aryl, phosphinyl, alkoxycarbonyl, sulfonyl) at the cumulenic C3 position were prepared by using a diverse range of synthetic strategies and converted into their respective 1-(2-hydroxy)-ethoxy-2-substituted...

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Veröffentlicht in:	Chemistry : a European journal 2013-11, Vol.19 (47), p.16093-16103
Hauptverfasser:	Alajarin, Mateo, Bonillo, Baltasar, Marin-Luna, Marta, Sanchez-Andrada, Pilar, Vidal, Angel
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Alternative energy sources Atoms & subatomic particles Carbon Cascades Chemistry Fragmentation Mathematical models Migration Toluene
Online-Zugang:	Volltext
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