Ligand-Metal Cooperating PC(sp3)P Pincer Complexes as Catalysts in Olefin Hydroformylation

Ligand-Metal Cooperating PC(sp3)P Pincer Complexes as Catalysts in Olefin Hydroformylation

Ligand–metal cooperation: A new ligand–metal cooperating catalyst for the hydroformylation of olefins is described (see scheme). The mechanism of the H2 activation and CH bond formation of the catalyst involves an intramolecular cooperation between the structurally remote functionality and the meta...

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Veröffentlicht in:Chemistry : a European journal 2013-12, Vol.19 (50), p.16906-16909
Hauptverfasser: Musa, Sanaa, Filippov, Oleg A., Belkova, Natalia V., Shubina, Elena S., Silantyev, Gleb A., Ackermann, Lutz, Gelman, Dmitri
Format: Artikel
Sprache:eng
Schlagworte:
Activation
Bonding
Catalysis
Catalysts
Chemistry
Cooperation
hydroformylation
ligand-metal cooperation
noninnocent ligands
Olefins
pincer complexes
Valence
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Zusammenfassung:Ligand–metal cooperation: A new ligand–metal cooperating catalyst for the hydroformylation of olefins is described (see scheme). The mechanism of the H2 activation and CH bond formation of the catalyst involves an intramolecular cooperation between the structurally remote functionality and the metal center and proceeds without change of the oxidation state of the metal.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201303311