Size-Regulable Vesicles Based on Anion-π Interactions

Size-Regulable Vesicles Based on Anion-π Interactions

Taking tetraoxacalix[2]arene[2]triazine as a functionalization platform, a series of new amphiphilic molecules were synthesized in 18 to 53 % yields by using a fragment coupling protocol. These amphiphilic molecules self‐assembled into stable vesicles in a mixture of THF and water, with the surface...

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Veröffentlicht in:Chemistry : a European journal 2014-06, Vol.20 (24), p.7486-7491
Hauptverfasser: He, Qing, Han, Yuchun, Wang, Yilin, Huang, Zhi-Tang, Wang, De-Xian
Format: Artikel
Sprache:eng
Schlagworte:
Anions
Binding
calixarenes
Chlorides
Control
Coupling (molecular)
Holes
noncovalent interactions
Platforms
self-assembly
Vesicles
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Zusammenfassung:Taking tetraoxacalix[2]arene[2]triazine as a functionalization platform, a series of new amphiphilic molecules were synthesized in 18 to 53 % yields by using a fragment coupling protocol. These amphiphilic molecules self‐assembled into stable vesicles in a mixture of THF and water, with the surface of the vesicles engineered by electron‐deficient cavities. Various anions are able to selectively influence the size of self‐assembled vesicles, following the order of F−
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201400074