Chirality Induction by Formation of Assembled Structures Based on Anion-Responsive π-Conjugated Molecules

Anion‐responsive π‐conjugated compounds having chiral alkyl chains were synthesized. Circular dichroism (CD) and circularly polarized luminescence (CPL) were observed in the solution‐state assemblies of the chiral anion receptors and those of their anion complexes as salts of a planar triazatriangulenium cation. The CD and CPL spectral patterns of the ion‐pair‐based assemblies were completely opposite to those of the anion‐free assemblies, and this suggests that anion binding and subsequent ion pairing change the chirality of the assembly modes. Opposite signs of the circular dichroism (CD) and circularly polarized luminescence (CPL) spectral patterns of ion‐pair‐based assemblies and anion‐free assemblies of anion‐responsive π‐conjugated compounds bearing chiral alkyl chains (see figure) suggest that anion binding and subsequent ion pairing change the chirality of the assembly modes.