One-Pot Synthesis of Arylketones from Aromatic Acids via Palladium-Catalyzed Suzuki Coupling

One-Pot Synthesis of Arylketones from Aromatic Acids via Palladium-Catalyzed Suzuki Coupling

A palladium-catalyzed one-pot procedure for the synthesis of aryl ketones has been developed. Triazine esters when coupled with aryl boronic acids provided aryl ketones in moderate to excellent yields (up to 95%) in the presence of 1 mol % Pd­(PPh3)2Cl2 for 30 min.

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Veröffentlicht in:Journal of organic chemistry 2016-04, Vol.81 (7), p.2987-2992
Hauptverfasser: Wu, Hongxiang, Xu, Baiping, Li, Yue, Hong, Fengying, Zhu, Dezhao, Jian, Junsheng, Pu, Xiaoer, Zeng, Zhuo
Format: Artikel
Sprache:eng
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Zusammenfassung:A palladium-catalyzed one-pot procedure for the synthesis of aryl ketones has been developed. Triazine esters when coupled with aryl boronic acids provided aryl ketones in moderate to excellent yields (up to 95%) in the presence of 1 mol % Pd­(PPh3)2Cl2 for 30 min.
ISSN:0022-3263
1520-6904
DOI:10.1021/acs.joc.5b02667