Ca(BH4)2-Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle

Ca(BH4)2-Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle

The Ca(BH4)2-Mg2NiH4 system presented here is, to the best of our knowledge, the first described Ca(BH4)2-based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi2.5B2 is formed upon dehydrogenation and the formation of Ca...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-04, Vol.52 (26), p.4836-4839
Hauptverfasser: Bergemann, N, Pistidda, C, Milanese, C, Emmler, T, Karimi, F, Chaudhary, A-L, Chierotti, M R, Klassen, T, Dornheim, M
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Sprache:eng
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Zusammenfassung:The Ca(BH4)2-Mg2NiH4 system presented here is, to the best of our knowledge, the first described Ca(BH4)2-based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi2.5B2 is formed upon dehydrogenation and the formation of Ca(BH4)2 upon rehydrogenation is confirmed.
ISSN:1364-548X
DOI:10.1039/c5cc09991a