Synthesis of a Novel 1,2,4-Oxadiazole Diterpene from the Oxime of the Methyl Ester of 1β,13-Epoxydihydroquinopimaric Acid

Synthesis of a Novel 1,2,4-Oxadiazole Diterpene from the Oxime of the Methyl Ester of 1β,13-Epoxydihydroquinopimaric Acid

Oximation of the dihydroquinopimaric acid O-cyanoethylderivative (2) via the amidoxime 3, and cyclization with trifluoroacetic anhydride resulted in a new 1,2,4-oxadiazole diterpenoid (4).

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Veröffentlicht in:Natural product communications 2016-01, Vol.11 (1), p.23-24
Hauptverfasser: Tretyakova, Elena V., Salimova, Elena V., Odinokov, Victor N., Dzhemilev, Usein M.
Format: Artikel
Sprache:eng
Schlagworte:
Diterpenes - chemical synthesis
Diterpenes - chemistry
Molecular Structure
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Zusammenfassung:Oximation of the dihydroquinopimaric acid O-cyanoethylderivative (2) via the amidoxime 3, and cyclization with trifluoroacetic anhydride resulted in a new 1,2,4-oxadiazole diterpenoid (4).
ISSN:1934-578X
1555-9475
DOI:10.1177/1934578X1601100108