Supercapacitive properties of composite electrode consisting of activated carbon and a quinone-containing conducting additive
•2,5-Bis((2-(1H-indol-3-yl)ethyl)amino)cyclohexa-2,5-diene-1,4-dione(HBU) is prepared.•Performance of the supercapacitor using carbon and HBU is improved.•The composite electrode is electrochemically stable in the redox process. A quinone-containing conducting additive, 2,5-bis((2-(1H-indol-3-yl)eth...
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Veröffentlicht in: | Synthetic metals 2015-05, Vol.203, p.31-36 |
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Hauptverfasser: | , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | •2,5-Bis((2-(1H-indol-3-yl)ethyl)amino)cyclohexa-2,5-diene-1,4-dione(HBU) is prepared.•Performance of the supercapacitor using carbon and HBU is improved.•The composite electrode is electrochemically stable in the redox process.
A quinone-containing conducting additive, 2,5-bis((2-(1H-indol-3-yl)ethyl)amino)cyclohexa 2,5-diene-1,4-dione (HBU) is synthesized and mixed with activated carbon as an active material to yield a composite supercapacitor electrode. Due to the extra redox reaction of hydroquinone/quinone couple, the supercapacitor adopting the composite electrode shows the enhancement of the electrochemical specific capacitance up to about 130Fg−1 in the scan range of 100–1000mVs−1 and over the repeated redox processes for 1000 cycles at 100mVs−1, compared to the case of activated carbon electrode alone (about 100Fg−1). The composite with the HBU is also electrochemically stable in the charge/discharge process and thereby can be highly recommended for supercapacitor electrode additive. |
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ISSN: | 0379-6779 1879-3290 |
DOI: | 10.1016/j.synthmet.2015.02.010 |