Supercapacitive properties of composite electrode consisting of activated carbon and a quinone-containing conducting additive

•2,5-Bis((2-(1H-indol-3-yl)ethyl)amino)cyclohexa-2,5-diene-1,4-dione(HBU) is prepared.•Performance of the supercapacitor using carbon and HBU is improved.•The composite electrode is electrochemically stable in the redox process. A quinone-containing conducting additive, 2,5-bis((2-(1H-indol-3-yl)eth...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Synthetic metals 2015-05, Vol.203, p.31-36
Hauptverfasser: Won, Jung Ha, Latifatu, Mohammed, Jang, Mi, Lee, Hae Soo, Kim, Beom-Cheol, Hamenu, Louis, Park, Jeong Ho, Kim, Kwang Man, Ko, Jang Myoun
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:•2,5-Bis((2-(1H-indol-3-yl)ethyl)amino)cyclohexa-2,5-diene-1,4-dione(HBU) is prepared.•Performance of the supercapacitor using carbon and HBU is improved.•The composite electrode is electrochemically stable in the redox process. A quinone-containing conducting additive, 2,5-bis((2-(1H-indol-3-yl)ethyl)amino)cyclohexa 2,5-diene-1,4-dione (HBU) is synthesized and mixed with activated carbon as an active material to yield a composite supercapacitor electrode. Due to the extra redox reaction of hydroquinone/quinone couple, the supercapacitor adopting the composite electrode shows the enhancement of the electrochemical specific capacitance up to about 130Fg−1 in the scan range of 100–1000mVs−1 and over the repeated redox processes for 1000 cycles at 100mVs−1, compared to the case of activated carbon electrode alone (about 100Fg−1). The composite with the HBU is also electrochemically stable in the charge/discharge process and thereby can be highly recommended for supercapacitor electrode additive.
ISSN:0379-6779
1879-3290
DOI:10.1016/j.synthmet.2015.02.010