Vanadium Oxide Nanowire-Carbon Nanotube Binder-Free Flexible Electrodes for Supercapacitors

Vanadium pentoxide (V2O5) layered nanostructures are known to have very stable crystal structures and high faradaic activity. The low electronic conductivity of V2O5 greatly limits the application of vanadium oxide as electrode materials and requires combining with conducting materials using binders. It is well known that the organic binders can degrade the overall performance of electrode materials and need carefully controlled compositions. In this study, we develop a simple method for preparing freestanding carbon nanotube (CNT)‐V2O5 nanowire (VNW) composite paper electrodes without using binders. Coin cell type (CR2032) supercapacitors are assembled using the nanocomposite paper electrode as the anode and high surface area carbon fiber electrode (Spectracarb 2225) as the cathode. The supercapacitor with CNT‐VNW composite paper electrode exhibits a power density of 5.26 kW Kg−1 and an energy density of 46.3 Wh Kg−1. (Li)VNWs and CNT composite paper electrodes can be fabricated in similar manner and show improved overall performance with a power density of 8.32 kW Kg−1 and an energy density of 65.9 Wh Kg−1. The power and energy density values suggest that such flexible hybrid nanocomposite paper electrodes may be useful for high performance electrochemical supercapacitors. Binder‐free flexible V2O5 nanowire (VNW)/carbon nanotube (CNT) composite paper electrodes are prepared for coin cell type (CR2032) supercapacitors. These composite paper electrodes show a highly porous VNW‐CNT network that facilitates Li+ ion and electron diffusion, resulting in high power and energy performance. Additionally, Li+ ions are introduced to the VNWs during the synthesis, which further enhances the power (8.32 kW kg−1) and energy (65.9 Wh Kg−1) densities with improved cycling stability.