Towards the tailored design of benzotriazinyl-based organic radicals displaying a spin transition

Towards the tailored design of benzotriazinyl-based organic radicals displaying a spin transition

The mechanism of the phase transition of 1-phenyl-3-trifluoromethyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl (1), the first reported triazinyl radical to present such a feature, is unveiled. In so doing, we identify the key ingredients that are crucial to enable the phase transition in this family of...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (87), p.15776-15779
Hauptverfasser: Fumanal, M, Vela, S, Novoa, J J, Ribas-Arino, J
Format: Artikel
Sprache:eng
Schlagworte:
Ingredients
Phase transformations
Radicals
Spin transition
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Beschreibung
Zusammenfassung:The mechanism of the phase transition of 1-phenyl-3-trifluoromethyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl (1), the first reported triazinyl radical to present such a feature, is unveiled. In so doing, we identify the key ingredients that are crucial to enable the phase transition in this family of radicals, and how those can be exploited by a rational design of the spin-carrying units.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc06288h