Employing a new 12-connected topological open-framework copper borovanadate as an effective heterogeneous catalyst for oxidation of benzyl-alkanes
A new 12-connected topological open-framework copper borovanadate with a unique B/V ratio (20/12) and a -B3O7(OH)-Na(μ-OH)[B(OH)2]-B3O7(OH)- connection mode has been hydrothermally obtained and characterized. It not only features the first 3-D copper(II) borovanadate which possesses the largest rati...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2015-01, Vol.44 (43), p.18731-18736 |
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| container_end_page | 18736 |
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| container_issue | 43 |
| container_start_page | 18731 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 44 |
| creator | Feng, Yuquan Ding, Chenghua Fan, Huitao Zhong, Zhiguo Qiu, Dongfang Shi, Hengzhen |
| description | A new 12-connected topological open-framework copper borovanadate with a unique B/V ratio (20/12) and a -B3O7(OH)-Na(μ-OH)[B(OH)2]-B3O7(OH)- connection mode has been hydrothermally obtained and characterized. It not only features the first 3-D copper(II) borovanadate which possesses the largest ratio of TM(2+) and borovanadate anion, but also displays highly catalytic activities for the oxidation of benzyl-alkanes. |
| doi_str_mv | 10.1039/c5dt03425f |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2015-01, Vol.44 (43), p.18731-18736 |
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| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Alkanes - chemistry Anions Benzyl Compounds - chemistry Boron Compounds - chemistry Catalysis Catalysts Catalytic activity Copper Copper - chemistry Displays Molecular Structure Oxidation Oxidation-Reduction Three dimensional Topology Vanadates - chemistry |
| title | Employing a new 12-connected topological open-framework copper borovanadate as an effective heterogeneous catalyst for oxidation of benzyl-alkanes |
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