Employing a new 12-connected topological open-framework copper borovanadate as an effective heterogeneous catalyst for oxidation of benzyl-alkanes

Employing a new 12-connected topological open-framework copper borovanadate as an effective heterogeneous catalyst for oxidation of benzyl-alkanes

A new 12-connected topological open-framework copper borovanadate with a unique B/V ratio (20/12) and a -B3O7(OH)-Na(μ-OH)[B(OH)2]-B3O7(OH)- connection mode has been hydrothermally obtained and characterized. It not only features the first 3-D copper(II) borovanadate which possesses the largest rati...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2015-01, Vol.44 (43), p.18731-18736
Hauptverfasser: Feng, Yuquan, Ding, Chenghua, Fan, Huitao, Zhong, Zhiguo, Qiu, Dongfang, Shi, Hengzhen
Format: Artikel
Sprache:eng
Schlagworte:
Alkanes - chemistry
Anions
Benzyl Compounds - chemistry
Boron Compounds - chemistry
Catalysis
Catalysts
Catalytic activity
Copper
Copper - chemistry
Displays
Molecular Structure
Oxidation
Oxidation-Reduction
Three dimensional
Topology
Vanadates - chemistry
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Zusammenfassung:A new 12-connected topological open-framework copper borovanadate with a unique B/V ratio (20/12) and a -B3O7(OH)-Na(μ-OH)[B(OH)2]-B3O7(OH)- connection mode has been hydrothermally obtained and characterized. It not only features the first 3-D copper(II) borovanadate which possesses the largest ratio of TM(2+) and borovanadate anion, but also displays highly catalytic activities for the oxidation of benzyl-alkanes.
ISSN:1477-9226
1477-9234
DOI:10.1039/c5dt03425f