Low-Temperature and Hysteresis-Free Electron-Transporting Layers for Efficient, Regular, and Planar Structure Perovskite Solar Cells

With the aim of fully utilizing the low processing temperatures of perovskite solar cells, significant progress in replacing high temperature processed TiO2 by various low‐temperature solution processed electron transporting layers (LT‐ETLs) was recently reported. Here, recent progress in the development of LT‐ETLs for regular planar structure perovskite solar cells, which is essential for achieving high efficiency in parallel to avoiding hysteresis, is reviewed. In addition, the application of a novel hysteresis‐free LT‐ETLs for regular planar perovskite solar cells in our laboratory is briefly discussed. By incorporating a low temperature processed WOx nanoparticular layer in combination with a mixed fullerene functionalized self‐assembled monolayers (SAMs), a regular, planar structure, and hysteresis‐free perovskite solar cell with a maximum efficiency of almost 15% can be fabricated. Recent progress in the development of low temperature processed electron‐transporting layers for regular planar structure perovskite solar cells is reviewed. Moreover, the application of a novel mixed self‐assembled monolayers in hysteresis‐free perovskite solar cells is briefly discussed. The as‐fabricated perovskite solar cells show a maximum efficiency of almost 15%.