Distinctive Activation and Functionalization of Hydrocarbon C-H Bonds Initiated by CpW(NO)( eta super(3)-allyl)(CH sub(2)CMe sub(3)) Complexes

Distinctive Activation and Functionalization of Hydrocarbon C-H Bonds Initiated by CpW(NO)( eta super(3)-allyl)(CH sub(2)CMe sub(3)) Complexes

Converting hydrocarbon feedstocks into value-added chemicals continues to offer challenges to contemporary preparative chemists. A particularly important remaining challenge is the selective activation and functionalization of the C(sp super(3))-H linkages of alkanes, which are relatively abundant b...

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Veröffentlicht in:Accounts of chemical research 2014-02, Vol.47 (2), p.330-340-330-340
Hauptverfasser: Baillie, Rhett A, Legzdins, Peter
Format: Artikel
Sprache:eng
Schlagworte:
Activation
Alkanes
Chemists
Converting
Feedstock
Hydrocarbons
Inert
Linkages
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Zusammenfassung:Converting hydrocarbon feedstocks into value-added chemicals continues to offer challenges to contemporary preparative chemists. A particularly important remaining challenge is the selective activation and functionalization of the C(sp super(3))-H linkages of alkanes, which are relatively abundant but chemically inert.
ISSN:0001-4842
1520-4898
DOI:10.1021/ar400108p