An experimental investigation on the solubility of CO2 in aqueous solutions of phenol

New experimental results are reported for the solubility of carbon dioxide in aqueous solutions of phenol and for the density of the corresponding liquid solvent mixtures at about (314, 354, and 395)K at pressures between about 0.2MPa and 9.7MPa. The experimental results are evaluated to determine H...

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Veröffentlicht in:Fluid phase equilibria 2014-11, Vol.382, p.42-53
Hauptverfasser: Jödecke, Michael, Pérez-Salado Kamps, Álvaro, Xia, Jianzhong, Maurer, Gerd
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Sprache:eng
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Zusammenfassung:New experimental results are reported for the solubility of carbon dioxide in aqueous solutions of phenol and for the density of the corresponding liquid solvent mixtures at about (314, 354, and 395)K at pressures between about 0.2MPa and 9.7MPa. The experimental results are evaluated to determine Henry's constants for carbon dioxide (on the molality scale) and the partial molar volume of carbon dioxide at infinite dilution in such solutions at the same temperatures. Furthermore, correlations are presented that describe the new gas solubility data almost within experimental uncertainty.
ISSN:0378-3812
1879-0224
DOI:10.1016/j.fluid.2014.08.024