Monofluorination and Trifluoromethylation of BODIPY Dyes for Prolonged Single-Molecule Detection

Electrophilic monofluorination with Selectfluor and nucleophilic trifluoromethylation with the Ruppert–Prakesh reagent of dimethyl‐, tetramethyl‐ and pentamethyl‐substituted boron dipyrromethenes (BODIPY) are investigated. Monofluorinated dyes are synthesized with low yields (

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Bibliographische Detailangaben
Veröffentlicht in:	Chemphyschem 2016-02, Vol.17 (3), p.433-442
Hauptverfasser:	Huynh, Anh Minh, Menges, Johannes, Vester, Michael, Dier, Tobias, Huch, Volker, Volmer, Dietrich A., Jung, Gregor
Format:	Artikel
Sprache:	eng
Schlagworte:	Boron Compounds - analysis Boron Compounds - chemical synthesis Boron Compounds - chemistry chromophores Crystallography, X-Ray dyes/pigments Fluorescence fluorescence spectroscopy Fluorescent Dyes - analysis Fluorescent Dyes - chemical synthesis Fluorescent Dyes - chemistry Halogenation Methylation Models, Molecular Molecular Structure photophysics Spectrometry, Fluorescence Spectrum analysis
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Electrophilic monofluorination with Selectfluor and nucleophilic trifluoromethylation with the Ruppert–Prakesh reagent of dimethyl‐, tetramethyl‐ and pentamethyl‐substituted boron dipyrromethenes (BODIPY) are investigated. Monofluorinated dyes are synthesized with low yields (
ISSN:	1439-4235 1439-7641
DOI:	10.1002/cphc.201500869