Uranyl complexes with methyl derivatives of alicyclic dioximes
A reaction of uranyl dioxalate complexes with methyl derivatives of alicyclic α-dioximes, 3-methyl-1,2-cyclohexanedione dioxime and 3-methyl-1,2-cyclopentanedione dioxime, was studied. The structure of (CN 3 H 6 ) 4 [(UO 2 ) 2 (C 6 H 8 N 2 O 2 )(CO 3 )(C 2 O 4 ) 2 ] · (C 6 H 10 N 2 O 2 ) · 2H 2 O an...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2012-07, Vol.57 (7), p.945-952 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A reaction of uranyl dioxalate complexes with methyl derivatives of alicyclic α-dioximes, 3-methyl-1,2-cyclohexanedione dioxime and 3-methyl-1,2-cyclopentanedione dioxime, was studied. The structure of (CN
3
H
6
)
4
[(UO
2
)
2
(C
6
H
8
N
2
O
2
)(CO
3
)(C
2
O
4
)
2
] · (C
6
H
10
N
2
O
2
) · 2H
2
O and NH
4
(CN
3
H
6
)
3
[(UO
2
)
2
(C
7
H
10
N
2
O
2
)(CO
3
)(C
2
O
4
)
2
] · 2H
2
O based on binuclear complex anions with carbonate-dioximate fragment was studied by X-ray diffraction. |
|---|---|
| ISSN: | 0036-0236 1531-8613 |
| DOI: | 10.1134/S0036023612070054 |