Variation of delta 18O and delta D in precipitation and stream waters across the Kashmir Himalaya (India) to distinguish and estimate the seasonal sources of stream flow

The spatial and temporal distribution of delta 18O and delta D measurements of precipitation and stream waters were used to distinguish various sources and components of stream flow and to estimate their residence times in snow dominated mountainous catchments of Kashmir Himalaya. A marked spatial and seasonal variability of stable isotopes of oxygen and hydrogen was observed in precipitation with delta 18O and delta D varied from -12.98ppt to -0.58ppt and -74.5ppt to -11.1ppt, respectively during the period from November 2007 to January 2009. The seasonal changes in stable isotopes of precipitation with depleted and enriched 18O and 2H in January/March/May and July/September/November, respectively at each site are attributed to the seasonal changes in ambient temperature, precipitation, source of moisture and airmass trajectory. The mean altitude effect of -0.23ppt and -1.2ppt per 100m change in elevation for delta 18O and delta D, respectively, was observed based on amount weighted mean precipitation isotopic composition data. Unlike precipitation, less variability of stable isotopes of streams was found with delta 18O and delta D ranging from -11.56ppt to -6.26ppt and -65.4ppt to -36.4ppt, respectively, the depleted values being observed in the headwaters of the streams/tributaries and enriched values at lower elevations of the watersheds. The LMWL established for the Kashmir Himalayas, based on amount weighted monthly samples is delta D=7.59 ( plus or minus 0.32) delta 18O+11.79 ( plus or minus 2.07) (r2=0.96) with lower slope and intercept than GMWL, is very close to the LMWL for the western Himalayas. The seasonal regression lines suggest the effect of evaporation with lower slopes and intercepts except in winter. The results suggest that the winter precipitation (snow) dominantly contributes the annual stream flow with average snowmelt contribution of about 29% in early spring, 66% in late spring, 61% in summer while the baseflow contribution is found in the order of 40% in autumn season. The mean stream residence times (MRTs) varied from 6 to 12.4months. The longer MRT of the Liddar catchment is attributed to its complex topography and larger area.