Immobilization of atmospheric nitrogen by lower palladium carbonyl complexes

It has been experimentally shown that the action of nitrogen onto hydrochloric acid solutions containing carbonylchloride complexes of palladium in lower oxidation states at room temperature and atmospheric pressure leads to its immobilization with the formation of ammonia. Some elements of the poss...

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Veröffentlicht in:	Russian journal of inorganic chemistry 2013-07, Vol.58 (7), p.766-768
1. Verfasser:	Fedoseev, I. V.
Format:	Artikel
Sprache:	eng
Schlagworte:	Ammonia Atmospheric pressure Barometric pressure Carbonyls Chemistry Chemistry and Materials Science Hydrochloric acid Immobilization Inorganic Chemistry Palladium Synthesis and Properties of Inorganic Compounds Valence
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Beschreibung
Zusammenfassung:	It has been experimentally shown that the action of nitrogen onto hydrochloric acid solutions containing carbonylchloride complexes of palladium in lower oxidation states at room temperature and atmospheric pressure leads to its immobilization with the formation of ammonia. Some elements of the possible mechanism of the immobilization of nitrogen have been discussed.
ISSN:	0036-0236 1531-8613
DOI:	10.1134/S0036023613070061