A homoleptic tetravalent cerium silylamide

A homoleptic tetravalent cerium silylamide

Treatment of Ce[N(SiHMe(2))(2)](3)(thf)(2) with the chlorinating agents PhICl(2), Ph(3)CCl or C(2)Cl(6) gave the homoleptic Ce(IV) silylamide Ce[N(SiHMe(2))(2)](4). When performed in the absence of donating (solvent) molecules, the trivalent cluster Ce(5)[N(SiHMe(2))(2)](8)Cl(7) was isolated.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (1), p.87-89
Hauptverfasser: Crozier, Alan R, Bienfait, Andre M, Maichle-Mössmer, Cäcilia, Törnroos, Karl W, Anwander, Reiner
Format: Artikel
Sprache:eng
Schlagworte:
Cerium
Chlorination
Clusters
Solvents
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Zusammenfassung:Treatment of Ce[N(SiHMe(2))(2)](3)(thf)(2) with the chlorinating agents PhICl(2), Ph(3)CCl or C(2)Cl(6) gave the homoleptic Ce(IV) silylamide Ce[N(SiHMe(2))(2)](4). When performed in the absence of donating (solvent) molecules, the trivalent cluster Ce(5)[N(SiHMe(2))(2)](8)Cl(7) was isolated.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc37404h