Carbon quantum dots/SnO sub(2)-Co sub(3)O sub(4) composite for highly efficient electrochemical water oxidation

Nanocomposites based on transition metal oxides (Co sub(3)O sub(4), etc.) and carbon nanostructures with low-cost, high activity and good stability are promising catalysts toward electrochemical water oxidation, which is desirable but remains challenging. Here, we report the design and synthesis of nanocomposite based on carbon quantum dots (CQDs), SnO sub(2) and Co sub(3)O sub(4) (CQDs/SnO sub(2)-Co sub(3)O sub(4)) as the electrocatalyst for highly efficient oxygen evolution reaction (OER). In alkaline media, the complex exhibited high electrocatalytic activity and long-term stability, which was better than either pristine Co sub(3)O sub(4) or SnO sub(2)-Co sub(3)O sub(4 ) composite. Moreover, the CQDs/SnO sub(2)-Co sub(3)O sub(4) with a molar ratio of Sn:Co at 1:3 revealed the highest catalytic activity toward OER among different molar ratios of CQDs/SnO sub(2)-Co sub(3)O sub(4) composites. Experimental results indicated that the Co atoms were considered as the active centre, the nano-sized SnO sub(2) enhanced electronic conductivity and the insoluble CQDs layer on the surface effectively protected the catalyst, thus the composite structure resulted in the excellent electrocatalytic activity and high stability.