Reinforcement of guest selectivity through the self-assembly of host molecules: selective recognition of lithium ions by dimerizable tricarboxylic acids

Reinforcement of guest selectivity through the self-assembly of host molecules: selective recognition of lithium ions by dimerizable tricarboxylic acids

C3-Symmetric tricarboxylic acids form dimers through intermolecular hydrogen bonds in nonpolar organic solvents. These dimers recognize lithium ions with high selectivities through the formation of 1 : 1 host-guest complexes between the collapsed dimeric assemblies and guest molecules.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-08, Vol.51 (65), p.12920-12923
Hauptverfasser: Minodani, Shoichi, Owaki, Masaki, Sano, Shuhei, Tsuzuki, Seiji, Yamanaka, Masamichi
Format: Artikel
Sprache:eng
Schlagworte:
Dimers
Hydrogen bonds
Lithium ions
Recognition
Reinforcement
Selectivity
Self assembly
Solvents
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Beschreibung
Zusammenfassung:C3-Symmetric tricarboxylic acids form dimers through intermolecular hydrogen bonds in nonpolar organic solvents. These dimers recognize lithium ions with high selectivities through the formation of 1 : 1 host-guest complexes between the collapsed dimeric assemblies and guest molecules.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc05227k