Ruthenium(ii)-catalyzed switchable C3-alkylation versusalkenylation with acrylates of 2-pyridylbenzofurans viaC-H bond activation

Ruthenium(ii)-catalyzed switchable C3-alkylation versusalkenylation with acrylates of 2-pyridylbenzofurans viaC-H bond activation

We documented an interesting observation of ruthenium(ii)-catalyzed benzofuran C-H activation and subsequent functionalization with acrylates that reveals that a simple base can switch the process from alkylation to alkenylation.

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Veröffentlicht in:Catalysis science & technology 2014-02, Vol.5 (1), p.114-117
Hauptverfasser: Kommagalla, Yadagiri, Mullapudi, Venkanna Babu, Francis, Fredi, Ramana, Chepuri V
Format: Artikel
Sprache:eng
Schlagworte:
Acrylates
Activation
Alkylation
Bonding
Catalysis
Switches
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container_end_page 117
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container_title Catalysis science & technology
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creator Kommagalla, Yadagiri
Mullapudi, Venkanna Babu
Francis, Fredi
Ramana, Chepuri V
description We documented an interesting observation of ruthenium(ii)-catalyzed benzofuran C-H activation and subsequent functionalization with acrylates that reveals that a simple base can switch the process from alkylation to alkenylation.
doi_str_mv 10.1039/c4cy01268b
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Acrylates
Activation
Alkylation
Bonding
Catalysis
Switches
title Ruthenium(ii)-catalyzed switchable C3-alkylation versusalkenylation with acrylates of 2-pyridylbenzofurans viaC-H bond activation
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