Ruthenium(ii)-catalyzed switchable C3-alkylation versusalkenylation with acrylates of 2-pyridylbenzofurans viaC-H bond activation

Ruthenium(ii)-catalyzed switchable C3-alkylation versusalkenylation with acrylates of 2-pyridylbenzofurans viaC-H bond activation

We documented an interesting observation of ruthenium(ii)-catalyzed benzofuran C-H activation and subsequent functionalization with acrylates that reveals that a simple base can switch the process from alkylation to alkenylation.

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Veröffentlicht in:Catalysis science & technology 2014-02, Vol.5 (1), p.114-117
Hauptverfasser: Kommagalla, Yadagiri, Mullapudi, Venkanna Babu, Francis, Fredi, Ramana, Chepuri V
Format: Artikel
Sprache:eng
Schlagworte:
Acrylates
Activation
Alkylation
Bonding
Catalysis
Switches
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Beschreibung
Zusammenfassung:We documented an interesting observation of ruthenium(ii)-catalyzed benzofuran C-H activation and subsequent functionalization with acrylates that reveals that a simple base can switch the process from alkylation to alkenylation.
ISSN:2044-4753
2044-4761
DOI:10.1039/c4cy01268b