The influence of yttrium dopant on the properties of anatase nanoparticles and the performance of dye-sensitized solar cells

TiO2 mesoporous nanoparticles (NPs) doped with yttrium (Y) ions are fabricated via an environmentally friendly and facile solvothermal method to serve as a photoanode for dye sensitized solar cells (DSSCs). X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy and N2...

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Veröffentlicht in:Physical chemistry chemical physics : PCCP 2015-01, Vol.17 (22), p.14836-14842
Hauptverfasser: Zhao, Bingxin, Wang, Jinshu, Li, Hongyi, Wang, Hong, Jia, Xinjian, Su, Penglei
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Sprache:eng
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Zusammenfassung:TiO2 mesoporous nanoparticles (NPs) doped with yttrium (Y) ions are fabricated via an environmentally friendly and facile solvothermal method to serve as a photoanode for dye sensitized solar cells (DSSCs). X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy and N2 adsorption-desorption tests are used to characterize the influence of yttrium dopant on the properties of TiO2 NPs. The prepared Y-doped TiO2 NPs show the anatase phase and exhibit Ti-O-Y bonds. The photovoltaic performance is primarily associated with the morphological parameters of the NPs. At the optimum Y concentration of 3 at%, the short circuit current density increased from 13.20 to 15.74 mA cm(-2), full sun solar power conversion efficiencies increased from 6.09% up to 7.61% as compared to the blank DSSC.
ISSN:1463-9076
1463-9084
DOI:10.1039/c5cp01178g