Extensive Study of Shape and Surface Structure Formation in the Mercury Beating Heart System

A phenomenological study of the mercury beating heart system in a three electrode electrochemical cell configuration forced with a harmonic perturbation is presented. The system is controlled via a potentiostat, where the mercury drop is electrically connected to a platinum wire and acts as the work...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2014-11, Vol.118 (45), p.10673-10678
Hauptverfasser: Ramírez-Álvarez, E, Ocampo-Espindola, J. L, Montoya, Fernando, Yousif, F, Vázquez, F, Rivera, M
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Sprache:eng
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Zusammenfassung:A phenomenological study of the mercury beating heart system in a three electrode electrochemical cell configuration forced with a harmonic perturbation is presented. The system is controlled via a potentiostat, where the mercury drop is electrically connected to a platinum wire and acts as the working electrode. This configuration exhibits geometrical shapes and complex surface structures when a harmonic signal is superimposed to the working electrode potential. This study involves a wide range of frequencies and amplitudes of the forcing signal. Differents levels of structure complexity are observed as a function of the parameters of the applied perturbation. At certain amplitudes and frequencies, rotational behavior is also observed.
ISSN:1089-5639
1520-5215
DOI:10.1021/jp507596b