Solution-Processed Metal Oxides as Efficient Carrier Transport Layers for Organic Photovoltaics

Carrier (electron and hole) transport layers (CTLs) are essential components for boosting the performance of various organic optoelectronic devices such as organic solar cells and organic light‐emitting diodes. Considering the drawbacks of conventional CTLs (easily oxidized/unstable, demanding/costly fabrication, etc.), transition metal oxides with good carrier transport/extraction and superior stability have drawn extensive research interest as CTLs for next‐generation devices. In recent years, many research efforts have been made toward the development of solution‐based metal oxide CTLs with the focus on low‐ or even room‐temperature processes, which can potentially be compatible with the deposition processes of organic materials and can significantly contribute to the low‐cost and scale‐up of organic devices. Here, the recent progress of different types of solution‐processed metal oxide CTLs are systematically reviewed in the context of organic photovoltaics, from synthesis approaches to device performance. Different approaches for further enhancing the performance of solution‐based metal oxide CTLs are also discussed, which may push the future development of this exciting field. Solution‐processed metal oxides as carrier transport layers play a key role in addressing the device stability and cost consideration for developing low‐cost, high‐performance organic optoelectronics such as organic solar cells and organic light‐emitting diodes. Here, recent progress of various types of solution‐processed metal oxides in the context of organic photovoltaic devices is systematically reviewed.