Topology-guided design of an anionic bor-network for photocatalytic [Ru(bpy)3](2+) encapsulation

Topology-guided design of an anionic bor-network for photocatalytic [Ru(bpy)3](2+) encapsulation

An anionic metal-organic framework, PCN-99, has been synthesized through a topology-guided strategy; its underlying bor-net is realized by the use of a tetrahedral [In(COO)4](-) node and a judiciously designed trigonal planar linker. In light of its anionic nature, the inherent cuboctahedral cage an...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (9), p.1926-1929
Hauptverfasser: Wang, Xuan, Lu, Weigang, Gu, Zhi-Yuan, Wei, Zhangwen, Zhou, Hong-Cai
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Photochemical Processes
Ruthenium Compounds - chemistry
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Zusammenfassung:An anionic metal-organic framework, PCN-99, has been synthesized through a topology-guided strategy; its underlying bor-net is realized by the use of a tetrahedral [In(COO)4](-) node and a judiciously designed trigonal planar linker. In light of its anionic nature, the inherent cuboctahedral cage and 1D channel make PCN-99 an excellent matrix to encapsulate the photocatalytic [Ru(bpy)3](2+).
ISSN:1364-548X
DOI:10.1039/c5cc08614k