C-Alkylation of Ketones and Related Compounds by Alcohols: Transition-Metal-Catalyzed Dehydrogenation

Transition‐metal‐catalyzed C‐alkylation of ketones and secondary alcohols, with alcohols, avoids use of organometallic or environmentally unfriendly alkylating agents by means of borrowing hydrogen (BH) or hydrogen autotransfer (HA) activation of the alcohol substrates. Water is formed as the only b...

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-01, Vol.55 (3), p.862-875
Hauptverfasser:	Huang, Fei, Liu, Zhuqing, Yu, Zhengkun
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Alcohol Alcohols Alkylating agents Alkylation Benign Bonding borrowing hydrogen Byproducts Catalysts Dehydrogenation Economics green chemistry Hydrogen Hydrogen storage Ketones Metals Rendering Reviews Substrates transition metals
Online-Zugang:	Volltext
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