Para-Selective Cu-Catalyzed C–H Aryloxylation of Electron-Rich Arenes and Heteroarenes

Para-Selective Cu-Catalyzed C–H Aryloxylation of Electron-Rich Arenes and Heteroarenes

Cu-catalyzed reaction of phenols with electron-rich arene or heteroarene ligands of unsymmetrical diaryl-λ3-iodanes is a key step in the developed one-pot two-step method for intermolecular para-selective C–H aryloxylation of heteroarenes and arenes.

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Veröffentlicht in:Journal of organic chemistry 2016-01, Vol.81 (2), p.371-379
Hauptverfasser: Sokolovs, Igors, Suna, Edgars
Format: Artikel
Sprache:eng
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Zusammenfassung:Cu-catalyzed reaction of phenols with electron-rich arene or heteroarene ligands of unsymmetrical diaryl-λ3-iodanes is a key step in the developed one-pot two-step method for intermolecular para-selective C–H aryloxylation of heteroarenes and arenes.
ISSN:0022-3263
1520-6904
DOI:10.1021/acs.joc.5b02728