Flux growth and characterization of Sr sub(2)NiWO sub(6) single crystals

Single crystals of the double perovskite Sr sub(2)NiWO sub(6) were synthesized via SrCl sub(2) flux growth using high quality, phase-pure polycrystalline Sr sub(2)NiWO sub(6) as precursor material. This high quality precursor enabled us to grow large and phase pure crystals with sizes up to 1 mm x 1...

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Veröffentlicht in:Journal of crystal growth 2015-07, Vol.421, p.39-44
Hauptverfasser: Blum, C GF, Holcombe, A, Gellesch, M, Sturza, M I, Rodan, S, Morrow, R, Maljuk, A, Woodward, P, Morris, P, Wolter, A UB, Buchner, B, Wurmehl, S
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Sprache:eng
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Zusammenfassung:Single crystals of the double perovskite Sr sub(2)NiWO sub(6) were synthesized via SrCl sub(2) flux growth using high quality, phase-pure polycrystalline Sr sub(2)NiWO sub(6) as precursor material. This high quality precursor enabled us to grow large and phase pure crystals with sizes up to 1 mm x 1 mm in the basal plane and octahedral morphology. We measured the temperature dependence of the magnetization along the c-axis and along the ab plane. The analysis of the data allows a precise determination of the effective magnetic moment and the Curie-Weiss temperature. Sr sub(2)NiWO sub(6) orders antiferromagnetically at TN=54 K as revealed by magnetization and specific heat data.
ISSN:0022-0248
DOI:10.1016/j.jcrysgro.2015.04.004