Case of the Missing Isomer: Pathways for Molecular Elimination in the Photoinduced Decomposition of 1,1-Dibromoethane

We report an experimental and computational study of the photodecomposition pathways of a prototypical gem-dihalide, 1,1-dibromoethane (1,1-EDB), in the condensed phase. Following photolysis of the matrix isolated parent compound in Ar at 5 K, photoproducts are observed corresponding to Br2 eliminat...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2013-11, Vol.117 (46), p.11915-11923
Hauptverfasser:	Kalume, Aimable, George, Lisa, Cunningham, Nicole, Reid, Scott A
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Computation Decomposition reactions Dynamical systems Dynamics Ethylene Dibromide - chemistry Exact sciences and technology Free radicals chemistry General and physical chemistry Isomers Organic chemistry Parents Pathways Photochemistry Photolysis Photolysis - radiation effects Physical chemistry of induced reactions (with radiations, particles and ultrasonics) Quantum Theory Reactivity and mechanisms
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