Improved mechanical stability of HKUST-1 in confined nanospace

Improved mechanical stability of HKUST-1 in confined nanospace

One of the main concerns in the technological application of several metal-organic frameworks (MOFs) relates to their structural instability under pressure (after a conforming step). Here we report for the first time that mechanical instability can be highly improved via nucleation and growth of MOF...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-09, Vol.51 (75), p.14191-14194
Hauptverfasser: Casco, M E, Fernández-Catalá, J, Martínez-Escandell, M, Rodríguez-Reinoso, F, Ramos-Fernández, E V, Silvestre-Albero, J
Format: Artikel
Sprache:eng
Schlagworte:
Activated carbon
Carbon - chemistry
Instability
Molecular Structure
Nanocrystals
Nanoparticles - chemistry
Nanostructure
Organometallic Compounds - chemistry
Stability
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Beschreibung
Zusammenfassung:One of the main concerns in the technological application of several metal-organic frameworks (MOFs) relates to their structural instability under pressure (after a conforming step). Here we report for the first time that mechanical instability can be highly improved via nucleation and growth of MOF nanocrystals in the confined nanospace of activated carbons.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc05107j