Chiral template induced homochiral MOFs built from achiral components: SHG enhancement and enantioselective sensing of chiral alkamines by ion-exchange

Chiral template induced homochiral MOFs built from achiral components: SHG enhancement and enantioselective sensing of chiral alkamines by ion-exchange

A pair of chiral template induced anionic homochiral frameworks constructed from achiral components has been synthesized. Ion-exchange of counter cations with polar or chiral organic cations enhances the SHG efficiency of the frameworks. The enantioselective sensing of chiral alkamines can be achiev...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (77), p.14481-14484
Hauptverfasser: Han, Yun-Hu, Liu, Yue-Cheng, Xing, Xiu-Shuang, Tian, Chong-Bin, Lin, Ping, Du, Shao-Wu
Format: Artikel
Sprache:eng
Schlagworte:
Cations
Construction
Detection
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Zusammenfassung:A pair of chiral template induced anionic homochiral frameworks constructed from achiral components has been synthesized. Ion-exchange of counter cations with polar or chiral organic cations enhances the SHG efficiency of the frameworks. The enantioselective sensing of chiral alkamines can be achieved by the SHG response.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc05566k