Halogen bonding-enhanced electrochemical halide anion sensing by redox-active ferrocene receptors

Halogen bonding-enhanced electrochemical halide anion sensing by redox-active ferrocene receptors

The first examples of halogen bonding redox-active ferrocene receptors and their anion electrochemical sensing properties are reported. Halogen bonding was found to significantly amplify the magnitude of the receptor's metallocene redox-couple's voltammetric responses for halide sensing co...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-10, Vol.51 (78), p.14640-14643
Hauptverfasser: Lim, Jason Y C, Cunningham, Matthew J, Davis, Jason J, Beer, Paul D
Format: Artikel
Sprache:eng
Schlagworte:
Anions
Bonding
Detection
Ferrocenes
Ferrous Compounds - chemistry
Halides
Halogens
Halogens - chemistry
Hydrogen bonding
Metallocenes
Oxidation-Reduction
Receptors
Receptors, Cell Surface - chemistry
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container_end_page 14643
container_issue 78
container_start_page 14640
container_title Chemical communications (Cambridge, England)
container_volume 51
creator Lim, Jason Y C
Cunningham, Matthew J
Davis, Jason J
Beer, Paul D
description The first examples of halogen bonding redox-active ferrocene receptors and their anion electrochemical sensing properties are reported. Halogen bonding was found to significantly amplify the magnitude of the receptor's metallocene redox-couple's voltammetric responses for halide sensing compared to their hydrogen bonding analogues in both acetonitrile and aqueous-acetonitrile solvent media.
doi_str_mv 10.1039/c5cc05704c
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source MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Anions
Bonding
Detection
Ferrocenes
Ferrous Compounds - chemistry
Halides
Halogens
Halogens - chemistry
Hydrogen bonding
Metallocenes
Oxidation-Reduction
Receptors
Receptors, Cell Surface - chemistry
title Halogen bonding-enhanced electrochemical halide anion sensing by redox-active ferrocene receptors
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