Halogen bonding-enhanced electrochemical halide anion sensing by redox-active ferrocene receptors

The first examples of halogen bonding redox-active ferrocene receptors and their anion electrochemical sensing properties are reported. Halogen bonding was found to significantly amplify the magnitude of the receptor's metallocene redox-couple's voltammetric responses for halide sensing co...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2015-10, Vol.51 (78), p.14640-14643
Hauptverfasser:	Lim, Jason Y C, Cunningham, Matthew J, Davis, Jason J, Beer, Paul D
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Bonding Detection Ferrocenes Ferrous Compounds - chemistry Halides Halogens Halogens - chemistry Hydrogen bonding Metallocenes Oxidation-Reduction Receptors Receptors, Cell Surface - chemistry
Online-Zugang:	Volltext
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Zusammenfassung:	The first examples of halogen bonding redox-active ferrocene receptors and their anion electrochemical sensing properties are reported. Halogen bonding was found to significantly amplify the magnitude of the receptor's metallocene redox-couple's voltammetric responses for halide sensing compared to their hydrogen bonding analogues in both acetonitrile and aqueous-acetonitrile solvent media.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c5cc05704c