Room-temperature selective oxidation of 2-naphthol to BINOL using a Au/SrTiO3-H2O2 catalytic system

Room-temperature selective oxidation of 2-naphthol to BINOL using a Au/SrTiO3-H2O2 catalytic system

Gold nanoparticle-loaded SrTiO3 (Au/SrTiO3) effectively catalyzes the selective C-C bond formation between 2-naphthol molecules to yield BINOL in the presence of H2O2, and the catalytic activity increases with decreasing Au particle size (d) in the range 2.6 ≤ d ≤ 8.9 nm.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-12, Vol.51 (100), p.17669-17671
Hauptverfasser: Naya, Shin-ichi, Hiramoto, Yuta, Teranishi, Miwako, Tada, Hiroaki
Format: Artikel
Sprache:eng
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Zusammenfassung:Gold nanoparticle-loaded SrTiO3 (Au/SrTiO3) effectively catalyzes the selective C-C bond formation between 2-naphthol molecules to yield BINOL in the presence of H2O2, and the catalytic activity increases with decreasing Au particle size (d) in the range 2.6 ≤ d ≤ 8.9 nm.
ISSN:1364-548X
DOI:10.1039/c5cc06438d