An improved synthesis of [26-2H3]castasterone
Commercially available epicastasterone has been employed as a starting material for the preparation of [26‐2H3]castasterone. The chemical synthesis has been realized in 13 chemical steps and 4.6% total yield. The target compound is intended to be used as internal standard for the quantitative analys...
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| Veröffentlicht in: | Journal of labelled compounds & radiopharmaceuticals 2015-11, Vol.58 (13-14), p.469-472 |
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| container_end_page | 472 |
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| container_issue | 13-14 |
| container_start_page | 469 |
| container_title | Journal of labelled compounds & radiopharmaceuticals |
| container_volume | 58 |
| creator | Zhabinskii, Vladimir N. Gulyakevich, Olga V. Kurman, Peter V. Shabunya, Polina S. Fatykhava, Svetlana A. Khripach, Vladimir A. |
| description | Commercially available epicastasterone has been employed as a starting material for the preparation of [26‐2H3]castasterone. The chemical synthesis has been realized in 13 chemical steps and 4.6% total yield. The target compound is intended to be used as internal standard for the quantitative analysis of brassinosteroids.
Commercially available epicastasterone has been employed as a starting material for the preparation of [26‐2H3]castasterone 1. The chemical synthesis has been realized in 13 chemical steps and 4.6% total yield. The target compound is intended to be used as internal standard for the quantitative analysis of brassinosteroids. |
| doi_str_mv | 10.1002/jlcr.3353 |
| format | Article |
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Commercially available epicastasterone has been employed as a starting material for the preparation of [26‐2H3]castasterone 1. The chemical synthesis has been realized in 13 chemical steps and 4.6% total yield. The target compound is intended to be used as internal standard for the quantitative analysis of brassinosteroids.</description><identifier>ISSN: 0362-4803</identifier><identifier>EISSN: 1099-1344</identifier><identifier>DOI: 10.1002/jlcr.3353</identifier><identifier>PMID: 26526489</identifier><identifier>CODEN: JLCRD4</identifier><language>eng</language><publisher>England: Blackwell Publishing Ltd</publisher><subject>brassinosteroids ; castasterone ; Cholestanols - chemical synthesis ; Cholestanols - chemistry ; deuterium ; epicastasterone ; Radiopharmaceuticals - chemical synthesis ; Radiopharmaceuticals - chemistry ; synthesis ; Tritium - chemistry</subject><ispartof>Journal of labelled compounds & radiopharmaceuticals, 2015-11, Vol.58 (13-14), p.469-472</ispartof><rights>Copyright © 2015 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4613-3355cbffe0b7b9acbc37eb57495ea61dab9da2f803d990d455641a7797cc99993</citedby><cites>FETCH-LOGICAL-c4613-3355cbffe0b7b9acbc37eb57495ea61dab9da2f803d990d455641a7797cc99993</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fjlcr.3353$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fjlcr.3353$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26526489$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhabinskii, Vladimir N.</creatorcontrib><creatorcontrib>Gulyakevich, Olga V.</creatorcontrib><creatorcontrib>Kurman, Peter V.</creatorcontrib><creatorcontrib>Shabunya, Polina S.</creatorcontrib><creatorcontrib>Fatykhava, Svetlana A.</creatorcontrib><creatorcontrib>Khripach, Vladimir A.</creatorcontrib><title>An improved synthesis of [26-2H3]castasterone</title><title>Journal of labelled compounds & radiopharmaceuticals</title><addtitle>J. Label Compd. Radiopharm</addtitle><description>Commercially available epicastasterone has been employed as a starting material for the preparation of [26‐2H3]castasterone. The chemical synthesis has been realized in 13 chemical steps and 4.6% total yield. The target compound is intended to be used as internal standard for the quantitative analysis of brassinosteroids.
Commercially available epicastasterone has been employed as a starting material for the preparation of [26‐2H3]castasterone 1. The chemical synthesis has been realized in 13 chemical steps and 4.6% total yield. The target compound is intended to be used as internal standard for the quantitative analysis of brassinosteroids.</description><subject>brassinosteroids</subject><subject>castasterone</subject><subject>Cholestanols - chemical synthesis</subject><subject>Cholestanols - chemistry</subject><subject>deuterium</subject><subject>epicastasterone</subject><subject>Radiopharmaceuticals - chemical synthesis</subject><subject>Radiopharmaceuticals - chemistry</subject><subject>synthesis</subject><subject>Tritium - chemistry</subject><issn>0362-4803</issn><issn>1099-1344</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp1kEFLwzAYhoMobk4P_gEpeNFDZtKkSXMcQzfHmCDqZCIhTVPs7NqZrOr-vRmdOwh-BL5Dnu_l5QHgFKMuRii8mhfadgmJyB5oYyQExITSfdBGhIWQxoi0wJFzc4T8H6WHoBWyKGQ0Fm0Ae2WQL5a2-jRp4Nbl6s243AVVFryEDIZD8qqVW_lnbFWaY3CQqcKZk-3ugMeb64f-EI7vBrf93hhqyjCBvkqkkywzKOGJUDrRhJsk4lRERjGcqkSkKsx8sVQIlNIoYhQrzgXXWvghHXDR5PpiH7VxK7nInTZFoUpT1U5iTlnMUUiYR8__oPOqtqVv5ylGCSVExJ66bChtK-esyeTS5gtl1xIjuXEoNw7lxqFnz7aJdbIw6Y78leaBqwb4yguz_j9Jjsb9-20kbC5yL_J7d6Hsu2Sc8EhOJwP5PJzOJqOnmcTkB-syiIc</recordid><startdate>201511</startdate><enddate>201511</enddate><creator>Zhabinskii, Vladimir N.</creator><creator>Gulyakevich, Olga V.</creator><creator>Kurman, Peter V.</creator><creator>Shabunya, Polina S.</creator><creator>Fatykhava, Svetlana A.</creator><creator>Khripach, Vladimir A.</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>201511</creationdate><title>An improved synthesis of [26-2H3]castasterone</title><author>Zhabinskii, Vladimir N. ; Gulyakevich, Olga V. ; Kurman, Peter V. ; Shabunya, Polina S. ; Fatykhava, Svetlana A. ; Khripach, Vladimir A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4613-3355cbffe0b7b9acbc37eb57495ea61dab9da2f803d990d455641a7797cc99993</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>brassinosteroids</topic><topic>castasterone</topic><topic>Cholestanols - chemical synthesis</topic><topic>Cholestanols - chemistry</topic><topic>deuterium</topic><topic>epicastasterone</topic><topic>Radiopharmaceuticals - chemical synthesis</topic><topic>Radiopharmaceuticals - chemistry</topic><topic>synthesis</topic><topic>Tritium - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhabinskii, Vladimir N.</creatorcontrib><creatorcontrib>Gulyakevich, Olga V.</creatorcontrib><creatorcontrib>Kurman, Peter V.</creatorcontrib><creatorcontrib>Shabunya, Polina S.</creatorcontrib><creatorcontrib>Fatykhava, Svetlana A.</creatorcontrib><creatorcontrib>Khripach, Vladimir A.</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of labelled compounds & radiopharmaceuticals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhabinskii, Vladimir N.</au><au>Gulyakevich, Olga V.</au><au>Kurman, Peter V.</au><au>Shabunya, Polina S.</au><au>Fatykhava, Svetlana A.</au><au>Khripach, Vladimir A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An improved synthesis of [26-2H3]castasterone</atitle><jtitle>Journal of labelled compounds & radiopharmaceuticals</jtitle><addtitle>J. Label Compd. Radiopharm</addtitle><date>2015-11</date><risdate>2015</risdate><volume>58</volume><issue>13-14</issue><spage>469</spage><epage>472</epage><pages>469-472</pages><issn>0362-4803</issn><eissn>1099-1344</eissn><coden>JLCRD4</coden><abstract>Commercially available epicastasterone has been employed as a starting material for the preparation of [26‐2H3]castasterone. The chemical synthesis has been realized in 13 chemical steps and 4.6% total yield. The target compound is intended to be used as internal standard for the quantitative analysis of brassinosteroids.
Commercially available epicastasterone has been employed as a starting material for the preparation of [26‐2H3]castasterone 1. The chemical synthesis has been realized in 13 chemical steps and 4.6% total yield. The target compound is intended to be used as internal standard for the quantitative analysis of brassinosteroids.</abstract><cop>England</cop><pub>Blackwell Publishing Ltd</pub><pmid>26526489</pmid><doi>10.1002/jlcr.3353</doi><tpages>4</tpages></addata></record> |
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| ispartof | Journal of labelled compounds & radiopharmaceuticals, 2015-11, Vol.58 (13-14), p.469-472 |
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| language | eng |
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| source | MEDLINE; Access via Wiley Online Library |
| subjects | brassinosteroids castasterone Cholestanols - chemical synthesis Cholestanols - chemistry deuterium epicastasterone Radiopharmaceuticals - chemical synthesis Radiopharmaceuticals - chemistry synthesis Tritium - chemistry |
| title | An improved synthesis of [26-2H3]castasterone |
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