Experimental Measurement of Carbon Dioxide Polarizability in the Solid State
We have experimentally determined the polarizability of CO 2 using the Lorentz–Lorenz equation by simultaneously measuring the density and the refractive index. The CO 2 conditions were solid phase, 10 - 7 mbar pressure, and temperature range 10–86 K. The polarizability value compares well with prev...
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Veröffentlicht in: | Journal of low temperature physics 2015-10, Vol.181 (1-2), p.1-9 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | We have experimentally determined the polarizability of
CO
2
using the Lorentz–Lorenz equation by simultaneously measuring the density and the refractive index. The
CO
2
conditions were solid phase,
10
-
7
mbar pressure, and temperature range 10–86 K. The polarizability value compares well with previous gas-phase experimental results and the results from simulations, and does not depend on the temperature of
CO
2
ice formation. This value is constant in the temperature range studied, despite a structural change from amorphous to crystalline. |
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ISSN: | 0022-2291 1573-7357 |
DOI: | 10.1007/s10909-015-1326-6 |