Synthesis of Substituted Sumanenes by Aromatic Electrophilic Substitution Reactions

Synthesis of Substituted Sumanenes by Aromatic Electrophilic Substitution Reactions

Electrophilic substitution reactions of sumanene were studied. Mono-, di-, and trisubstituted sumanenes were selectively prepared with the separation of all regioisomers. The regioselectivity was predicted well by the HOMO density values determined by DFT calculations.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 2013-04, Vol.42 (4), p.386-388
Hauptverfasser: Babu Shrestha, Binod, Karanjit, Sangita, Panda, Gautam, Higashibayashi, Shuhei, Sakurai, Hidehiro
Format: Artikel
Sprache:eng
Schlagworte:
Density
Mathematical analysis
Separation
Substitution reactions
Synthesis
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 388
container_issue 4
container_start_page 386
container_title Chemistry letters
container_volume 42
creator Babu Shrestha, Binod
Karanjit, Sangita
Panda, Gautam
Higashibayashi, Shuhei
Sakurai, Hidehiro
description Electrophilic substitution reactions of sumanene were studied. Mono-, di-, and trisubstituted sumanenes were selectively prepared with the separation of all regioisomers. The regioselectivity was predicted well by the HOMO density values determined by DFT calculations.
doi_str_mv 10.1246/cl.121273
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1744710766</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3184553021</sourcerecordid><originalsourceid>FETCH-LOGICAL-c482t-f91ed54268763d4c8f048d4c540ec66bf14bdbb45fdddac7c97c8fc8013fb3af3</originalsourceid><addsrcrecordid>eNplkE1LAzEYhIMoWKsH_8GCFz2s5muT9FiKX1AQrJ5DNpvQlN3NmmQP--9NaRHR08wLzzsMA8A1gvcIU_ag26wIc3ICZohQUUKOqlMwg4SxkkOMz8FFjDsIoVgQPAObzdSnrYkuFt4Wm7GOyaUxmSb7TvWmN7Gop2IZfKeS08Vja3QKfti6Nl8_vPN98W6U3pt4Cc6saqO5OuocfD49fqxeyvXb8-tquS41FTiVdoFMU1HMBGekoVpYSEXWikKjGastonVT17SyTdMozfWCZ0YLiIitibJkDm4PuUPwX6OJSXYuatO2ubcfo0ScUo4gZyyjN3_QnR9Dn9tJRLmArCJ5jzm4O1A6-BiDsXIIrlNhkgjK_bxSt_Iwb2bZkd2azumc5LUzadqpQfW_0v89fgM0hIEj</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1478065389</pqid></control><display><type>article</type><title>Synthesis of Substituted Sumanenes by Aromatic Electrophilic Substitution Reactions</title><source>Oxford University Press Journals All Titles (1996-Current)</source><creator>Babu Shrestha, Binod ; Karanjit, Sangita ; Panda, Gautam ; Higashibayashi, Shuhei ; Sakurai, Hidehiro</creator><creatorcontrib>Babu Shrestha, Binod ; Karanjit, Sangita ; Panda, Gautam ; Higashibayashi, Shuhei ; Sakurai, Hidehiro</creatorcontrib><description>Electrophilic substitution reactions of sumanene were studied. Mono-, di-, and trisubstituted sumanenes were selectively prepared with the separation of all regioisomers. The regioselectivity was predicted well by the HOMO density values determined by DFT calculations.</description><identifier>ISSN: 0366-7022</identifier><identifier>EISSN: 1348-0715</identifier><identifier>DOI: 10.1246/cl.121273</identifier><language>eng</language><publisher>Tokyo: The Chemical Society of Japan</publisher><subject>Density ; Mathematical analysis ; Separation ; Substitution reactions ; Synthesis</subject><ispartof>Chemistry letters, 2013-04, Vol.42 (4), p.386-388</ispartof><rights>The Chemical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2013</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c482t-f91ed54268763d4c8f048d4c540ec66bf14bdbb45fdddac7c97c8fc8013fb3af3</citedby><cites>FETCH-LOGICAL-c482t-f91ed54268763d4c8f048d4c540ec66bf14bdbb45fdddac7c97c8fc8013fb3af3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids></links><search><creatorcontrib>Babu Shrestha, Binod</creatorcontrib><creatorcontrib>Karanjit, Sangita</creatorcontrib><creatorcontrib>Panda, Gautam</creatorcontrib><creatorcontrib>Higashibayashi, Shuhei</creatorcontrib><creatorcontrib>Sakurai, Hidehiro</creatorcontrib><title>Synthesis of Substituted Sumanenes by Aromatic Electrophilic Substitution Reactions</title><title>Chemistry letters</title><addtitle>Chemistry Letters</addtitle><description>Electrophilic substitution reactions of sumanene were studied. Mono-, di-, and trisubstituted sumanenes were selectively prepared with the separation of all regioisomers. The regioselectivity was predicted well by the HOMO density values determined by DFT calculations.</description><subject>Density</subject><subject>Mathematical analysis</subject><subject>Separation</subject><subject>Substitution reactions</subject><subject>Synthesis</subject><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNplkE1LAzEYhIMoWKsH_8GCFz2s5muT9FiKX1AQrJ5DNpvQlN3NmmQP--9NaRHR08wLzzsMA8A1gvcIU_ag26wIc3ICZohQUUKOqlMwg4SxkkOMz8FFjDsIoVgQPAObzdSnrYkuFt4Wm7GOyaUxmSb7TvWmN7Gop2IZfKeS08Vja3QKfti6Nl8_vPN98W6U3pt4Cc6saqO5OuocfD49fqxeyvXb8-tquS41FTiVdoFMU1HMBGekoVpYSEXWikKjGastonVT17SyTdMozfWCZ0YLiIitibJkDm4PuUPwX6OJSXYuatO2ubcfo0ScUo4gZyyjN3_QnR9Dn9tJRLmArCJ5jzm4O1A6-BiDsXIIrlNhkgjK_bxSt_Iwb2bZkd2azumc5LUzadqpQfW_0v89fgM0hIEj</recordid><startdate>20130405</startdate><enddate>20130405</enddate><creator>Babu Shrestha, Binod</creator><creator>Karanjit, Sangita</creator><creator>Panda, Gautam</creator><creator>Higashibayashi, Shuhei</creator><creator>Sakurai, Hidehiro</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20130405</creationdate><title>Synthesis of Substituted Sumanenes by Aromatic Electrophilic Substitution Reactions</title><author>Babu Shrestha, Binod ; Karanjit, Sangita ; Panda, Gautam ; Higashibayashi, Shuhei ; Sakurai, Hidehiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c482t-f91ed54268763d4c8f048d4c540ec66bf14bdbb45fdddac7c97c8fc8013fb3af3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Density</topic><topic>Mathematical analysis</topic><topic>Separation</topic><topic>Substitution reactions</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Babu Shrestha, Binod</creatorcontrib><creatorcontrib>Karanjit, Sangita</creatorcontrib><creatorcontrib>Panda, Gautam</creatorcontrib><creatorcontrib>Higashibayashi, Shuhei</creatorcontrib><creatorcontrib>Sakurai, Hidehiro</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Babu Shrestha, Binod</au><au>Karanjit, Sangita</au><au>Panda, Gautam</au><au>Higashibayashi, Shuhei</au><au>Sakurai, Hidehiro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Substituted Sumanenes by Aromatic Electrophilic Substitution Reactions</atitle><jtitle>Chemistry letters</jtitle><addtitle>Chemistry Letters</addtitle><date>2013-04-05</date><risdate>2013</risdate><volume>42</volume><issue>4</issue><spage>386</spage><epage>388</epage><pages>386-388</pages><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>Electrophilic substitution reactions of sumanene were studied. Mono-, di-, and trisubstituted sumanenes were selectively prepared with the separation of all regioisomers. The regioselectivity was predicted well by the HOMO density values determined by DFT calculations.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/cl.121273</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0366-7022
ispartof Chemistry letters, 2013-04, Vol.42 (4), p.386-388
issn 0366-7022
1348-0715
language eng
recordid cdi_proquest_miscellaneous_1744710766
source Oxford University Press Journals All Titles (1996-Current)
subjects Density
Mathematical analysis
Separation
Substitution reactions
Synthesis
title Synthesis of Substituted Sumanenes by Aromatic Electrophilic Substitution Reactions
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-13T11%3A55%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20Substituted%20Sumanenes%20by%20Aromatic%20Electrophilic%20Substitution%20Reactions&rft.jtitle=Chemistry%20letters&rft.au=Babu%20Shrestha,%20Binod&rft.date=2013-04-05&rft.volume=42&rft.issue=4&rft.spage=386&rft.epage=388&rft.pages=386-388&rft.issn=0366-7022&rft.eissn=1348-0715&rft_id=info:doi/10.1246/cl.121273&rft_dat=%3Cproquest_cross%3E3184553021%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1478065389&rft_id=info:pmid/&rfr_iscdi=true