Synthesis of Substituted Sumanenes by Aromatic Electrophilic Substitution Reactions

Synthesis of Substituted Sumanenes by Aromatic Electrophilic Substitution Reactions

Electrophilic substitution reactions of sumanene were studied. Mono-, di-, and trisubstituted sumanenes were selectively prepared with the separation of all regioisomers. The regioselectivity was predicted well by the HOMO density values determined by DFT calculations.

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Veröffentlicht in:Chemistry letters 2013-04, Vol.42 (4), p.386-388
Hauptverfasser: Babu Shrestha, Binod, Karanjit, Sangita, Panda, Gautam, Higashibayashi, Shuhei, Sakurai, Hidehiro
Format: Artikel
Sprache:eng
Schlagworte:
Density
Mathematical analysis
Separation
Substitution reactions
Synthesis
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Zusammenfassung:Electrophilic substitution reactions of sumanene were studied. Mono-, di-, and trisubstituted sumanenes were selectively prepared with the separation of all regioisomers. The regioselectivity was predicted well by the HOMO density values determined by DFT calculations.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.121273