One-pot sequential deoximation and allylation reactions of aldoximes in aqueous solution

One-pot sequential deoximation and allylation reactions of aldoximes in aqueous solution

A simple procedure has been developed for conducting tin-mediated deoximation and allylation reactions of aldoximes in water to form homoallylic alcohols. Employing the new conditions, various homoallylic alcohols were produced in good to excellent yields. [Display omitted]

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Veröffentlicht in:Tetrahedron 2012-03, Vol.68 (12), p.2630-2635
Hauptverfasser: Lin, Mei-Huey, Lin, Long-Zhi, Chuang, Tsung-Hsun, Liu, Han-Jun
Format: Artikel
Sprache:eng
Schlagworte:
Alcohols
Aldoximes
Aliphatic compounds
Allyl compounds
Allylation
Aqueous solutions
Chemical reactions
Chemistry
Conduction
Deoximation
Exact sciences and technology
Homoallylic alcohols
Organic chemistry
Oximes
Preparations and properties
Tetrahedrons
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Zusammenfassung:A simple procedure has been developed for conducting tin-mediated deoximation and allylation reactions of aldoximes in water to form homoallylic alcohols. Employing the new conditions, various homoallylic alcohols were produced in good to excellent yields. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2012.01.074