Heterolytic dihydrogen activation by B(C sub(6)F sub(5)) sub(3) and carbonyl compounds

Heterolytic dihydrogen activation by B(C sub(6)F sub(5)) sub(3) and carbonyl compounds

Aromatic carbonyl compounds in combination with B(C sub(6)F sub(5)) sub(3) are able to activate H sub(2) heterolytically. The reactivity of the carbonyl-B(C sub(6)F sub(5)) sub(3) adduct is initiated by its thermal dissociation into components. After H sub(2) addition, aromatic carbonyl compounds co...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2012-03, Vol.41 (15), p.4310-4312
Hauptverfasser: Lindqvist, Markus, Sarnela, Nina, Sumerin, Victor, Chernichenko, Konstantin, Leskelae, Markku, Repo, Timo
Format: Artikel
Sprache:eng
Schlagworte:
Activation
Adducts
Alcohols
Aromatic compounds
Carbonyl compounds
Carbonyls
Methane
Thermal dissociation
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Aromatic carbonyl compounds in combination with B(C sub(6)F sub(5)) sub(3) are able to activate H sub(2) heterolytically. The reactivity of the carbonyl-B(C sub(6)F sub(5)) sub(3) adduct is initiated by its thermal dissociation into components. After H sub(2) addition, aromatic carbonyl compounds convert into aryl-substituted methanes or alcohols.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt12268e