Zn(ii), Cd(ii) and Cu(ii) complexes of 2,5-bis{N-(2,6-diisopropylphenyl)iminomethyl}pyrro le: synthesis, structures and their high catalytic activity for efficient cyclic carbonate synthesis

The syntheses of Zn(ii), Cd(ii) and Cu(ii) complexes of 2,5-bis{N-(2,6-diisopropylphenyl)iminomethyl}pyrro le (DIP sub(2)pyr)H 1 and their catalytic activities in CO sub(2) fixation are reported. The structures of these complexes were characterized by IR, super(1)H, super(13)C NMR and single crystal X-ray diffraction techniques. The catalytic activities of these complexes for the cycloaddition of CO sub(2) to an epoxide under one atmosphere of pressure and mild temperature conditions to yield cyclic carbonate have been studied. Among the four complexes synthesized, the Zn(ii) and Cu(ii) complexes were found to be versatile whereas the Cu(ii) complex was more selective in the conversion. They were highly effective for the conversion of monosubstituted terminal epoxides, disubstituted terminal and internal epoxides to their corresponding cyclic carbonates with good to high yields.