A metal-organic framework constructed using a flexible tripodal ligand and tetranuclear copper cluster for sensing small molecules

A metal-organic framework constructed using a flexible tripodal ligand and tetranuclear copper cluster for sensing small molecules

A new porous metal-organic framework (MOF) {[Cu4(OH)2(tci)2(bpy)2]·11H2O} (1) based on a tetranuclear copper cluster with intracluster antiferromagnetic interactions was synthesized. Quartz crystal microbalance (QCM) sensor studies reveal sensitive and selective sensing for small molecules.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2015-05, Vol.44 (17), p.7770-7773
Hauptverfasser: Hou, Chaoyi, Bai, Yue-Ling, Bao, XiaoLi, Xu, Liangzhen, Lin, Rong-Guang, Zhu, Shourong, Fang, Jianhui, Xu, Jiaqiang
Format: Artikel
Sprache:eng
Schlagworte:
Antiferromagnetism
Clusters
Construction
Copper
Detection
Ligands
Metal-organic frameworks
Microbalances
Quartz crystals
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Zusammenfassung:A new porous metal-organic framework (MOF) {[Cu4(OH)2(tci)2(bpy)2]·11H2O} (1) based on a tetranuclear copper cluster with intracluster antiferromagnetic interactions was synthesized. Quartz crystal microbalance (QCM) sensor studies reveal sensitive and selective sensing for small molecules.
ISSN:1477-9226
1477-9234
DOI:10.1039/c5dt00762c