Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution

Dinuclear complexes of tetravalent cerium in an aqueous perchloric acid solution

Primary aquo species of tetravalent cerium (Ce(IV)) in perchloric acid has been identified as a single oxo-bridging dinuclear complex, not a mononuclear one, by extended X-ray absorption fine structure (EXAFS) spectroscopy combined with density functional theory (DFT) calculations.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2012-06, Vol.41 (24), p.7190-7192
Hauptverfasser: Ikeda-Ohno, Atsushi, Tsushima, Satoru, Hennig, Christoph, Yaita, Tsuyoshi, Bernhard, Gert
Format: Artikel
Sprache:eng
Schlagworte:
Cerium
Density functional theory
Fine structure
Mathematical analysis
Perchloric acid
Spectroscopy
X-rays
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Zusammenfassung:Primary aquo species of tetravalent cerium (Ce(IV)) in perchloric acid has been identified as a single oxo-bridging dinuclear complex, not a mononuclear one, by extended X-ray absorption fine structure (EXAFS) spectroscopy combined with density functional theory (DFT) calculations.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt12406h