Activator-free and one-pot C-allylation by simple palladium catalyst in water
For atom economic and green chemistry concepts, we develop a reaction that involves one-pot and one step to construct the C–C bond without the help of any activating reagents for allylic alcohols in water. The palladium-catalyzed allylation of cyclic 1,3-diones using allylic alcohols directly gave t...
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| Veröffentlicht in: | Tetrahedron letters 2012-03, Vol.53 (11), p.1380-1384 |
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| creator | Shue, Yi-Jen Yang, Shyh-Chyun |
| description | For atom economic and green chemistry concepts, we develop a reaction that involves one-pot and one step to construct the C–C bond without the help of any activating reagents for allylic alcohols in water. The palladium-catalyzed allylation of cyclic 1,3-diones using allylic alcohols directly gave the corresponding allylated products in 8–99% yields. |
| doi_str_mv | 10.1016/j.tetlet.2012.01.022 |
| format | Article |
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| ispartof | Tetrahedron letters, 2012-03, Vol.53 (11), p.1380-1384 |
| issn | 0040-4039 1873-3581 |
| language | eng |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Activator-free Alcohols Allyl compounds Allylic alcohols Carbon-carbon composites Chemical bonds Chemical reactions Construction costs Cyclic 1,3-diones Economics Palladium Tetrahedrons Water |
| title | Activator-free and one-pot C-allylation by simple palladium catalyst in water |
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