Activator-free and one-pot C-allylation by simple palladium catalyst in water

Activator-free and one-pot C-allylation by simple palladium catalyst in water

For atom economic and green chemistry concepts, we develop a reaction that involves one-pot and one step to construct the C–C bond without the help of any activating reagents for allylic alcohols in water. The palladium-catalyzed allylation of cyclic 1,3-diones using allylic alcohols directly gave t...

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Veröffentlicht in:Tetrahedron letters 2012-03, Vol.53 (11), p.1380-1384
Hauptverfasser: Shue, Yi-Jen, Yang, Shyh-Chyun
Format: Artikel
Sprache:eng
Schlagworte:
Activator-free
Alcohols
Allyl compounds
Allylic alcohols
Carbon-carbon composites
Chemical bonds
Chemical reactions
Construction costs
Cyclic 1,3-diones
Economics
Palladium
Tetrahedrons
Water
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Beschreibung
Zusammenfassung:For atom economic and green chemistry concepts, we develop a reaction that involves one-pot and one step to construct the C–C bond without the help of any activating reagents for allylic alcohols in water. The palladium-catalyzed allylation of cyclic 1,3-diones using allylic alcohols directly gave the corresponding allylated products in 8–99% yields.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2012.01.022